dc.contributor.author | Tabari, Daniel S. | en |
dc.contributor.author | Tolentino, Daniel R. | en |
dc.contributor.author | Schrodi, Yann | en |
dc.date.accessioned | 2018-07-12T22:28:19Z | |
dc.date.available | 2018-07-12T22:28:19Z | |
dc.date.issued | 2013 | en |
dc.identifier.citation | Organometallics 32(1), 5-8. (2013) | en |
dc.identifier.issn | 0276-7333 | en |
dc.identifier.uri | http://hdl.handle.net/10211.3/204627 | en |
dc.description.abstract | 1st Generation Hoveyda-Grubbs olefin metathesis catalyst was purposely decomposed in the presence of ethylene yielding inorganic species that are inactive in the ring-closing metathesis (RCM) of benchmark substrate diethyldiallyl malonate (DEDAM). The decomposed catalyst was treated with 1-(3,5-diisopropoxyphenyl)-1-phenylprop-2-yn-1-ol (3) to generate an olefin metathesis active ruthenium indenylidene-ether complex in 43 % yield. This complex was also prepared independently by reacting RuCl2(p-cymene)(PCy3) with organic precursor 3. The activity of the isolated reactivated catalyst in the RCM of DEDAM is similar to that of the independently prepared complex. | en |
dc.format.extent | 4 pages | en |
dc.language.iso | en | en |
dc.publisher | American Chemical Society | en |
dc.relation.uri | doi.org/10.1021/om301042a | en |
dc.subject | Olefin metathesis | en |
dc.subject | catalyst reactivation | en |
dc.subject | ruthenium indenylidene | en |
dc.subject | RCM | en |
dc.title | Reactivation Of A Ruthenium-Based Olefin Metathesis Catalyst | en |
dc.type | Article | en |
File | Size | Format | View |
---|---|---|---|
There are no files associated with this item. |